Chlorinated VOCs

Hepure offers multiple proven treatment technologies for chlorinated volatile organic compounds (CVOCs) in soil and groundwater — from abiotic chemical reduction with zero valent iron to in situ chemical oxidation and enhanced bioremediation.

About chlorinated VOC contamination

Chlorinated volatile organic compounds are among the most common groundwater contaminants in the United States. They include solvents like trichloroethene (TCE), tetrachloroethene (PCE), and their degradation products — dichloroethene (DCE) and vinyl chloride.

These compounds are found at former industrial sites, dry cleaning facilities, military installations, and manufacturing plants where chlorinated solvents were used for degreasing, cleaning, and other processes.

Hepure’s ZVI powders are capable of treating chlorinated solvents abiotically, avoiding the production of harmful daughter products (DCE and VC). Additionally, Hepure’s permanganate and other chemical oxidants provide effective in situ chemical oxidation alternatives for CVOC treatment.

CVOCs treatable with Hepure products

The following chlorinated compounds can be addressed using Hepure’s remediation technologies. This list is based on documented treatment capabilities of our product line.

Tetrachloroethene (PCE)

Also known as perchloroethylene

Trichloroethene (TCE)

Common industrial degreaser

cis-1,2-Dichloroethene

TCE degradation product

trans-1,2-Dichloroethene

TCE degradation product

1,1-Dichloroethene

Vinylidene chloride

Vinyl Chloride

Final degradation product

Tetrachloromethane

Carbon tetrachloride

Trichloromethane

Chloroform

1,1,1-Trichloroethane

Methyl chloroform

1,1,2-Trichloroethane

Vinyl trichloride

Hexachloroethane

Industrial chemical

1,2,3-Trichloropropane

Industrial solvent

Treatment technologies for CVOCs

Hepure offers multiple treatment approaches for chlorinated solvents. The optimal choice depends on your site’s geology, contaminant concentrations, and clean-up goals.

Abiotic Reduction

Zero Valent Iron (Ferox ZVI)

ZVI powders treat chlorinated solvents abiotically, avoiding the production of harmful daughter products (DCE and VC). Since entering the market in 2000, Hepure’s Ferox iron powders have documented successful outcomes at more than 150 sites across North America. ZVI provides long-term treatment (3–15 years longevity) and is synergistic with follow-on bioremediation.

Ferox PRBFerox FlowFerox TargetFerox Plus (eZVI)
View ZVI Products →
Chemical Oxidation

Permanganate (ISCO)

Potassium permanganate (KMnO4) and sodium permanganate (NaMnO4) provide effective in situ chemical oxidation of chlorinated solvents. Permanganate is a well-established ISCO technology for treating CVOCs in groundwater.

Potassium Permanganate (KMnO4)Sodium Permanganate (NaMnO4)
View Permanganate Products →
Chemical Oxidation

Other Chemical Oxidants

Hepure’s additional oxidant products provide ISCO treatment options for CVOCs depending on site-specific conditions and treatment objectives.

Activated Persulfate (Na2S2O8)Hydrogen Peroxide (H2O2)
View All Oxidants →
Biological Treatment

Enhanced Anaerobic Bioremediation

Hepure provides electron donors and biological amendments to stimulate anaerobic reductive dechlorination of CVOCs. These can be used as standalone treatments or in combination with ZVI for enhanced performance.

Emulsified Vegetable OilSodium LactateFerox Plus (eZVI + EVO)
View Bioremediation Products →

Have a CVOC remediation challenge?

Contact our technical team to discuss your site conditions and contaminant profile. We’ll help you select the optimal treatment approach.